Low temperature heat capacities and thermodynamic functions described by Debye–Einstein integrals

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Low temperature heat capacities and thermodynamic functions described by Debye–Einstein integrals

Abstract Thermodynamic data of various crystalline solids are assessed from low temperature heat capacity measurements, i.e., from almost absolute zero to 300 K by means of semi-empirical models. Previous studies frequently present fit functions with a large amount of coefficients resulting in almost perfect agreement with experimental data. It is, however, pointed out in this work that special...

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ژورنال

عنوان ژورنال: Monatshefte für Chemie - Chemical Monthly

سال: 2018

ISSN: 0026-9247,1434-4475

DOI: 10.1007/s00706-017-2117-3