Lubrication Mechanism of Surface‐Attached Hydrogel Layers in Sliding Contact
نویسندگان
چکیده
Swollen, surface-attached hydrogel layers in sliding contact exhibit unusual friction properties. To study this phenomenon, covalently bonded to solid substrates are generated by CH insertion crosslinking. Brief UV irradiation of thin photoreactive prepolymers leads simultaneous crosslinking the polymer chains and attachment network substrate. As can only swell perpendicular surface, subchains on two sides pair cannot interpenetrate for entropic reasons, adhesion such pairs is negligible. In work, tribological behavior investigated as a function load velocity. It observed that very films, indentation accordingly strong film thickness role chain confinement lubrication hydrogels discussed. A model mechanism systems developed.
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ژورنال
عنوان ژورنال: Advanced Materials Interfaces
سال: 2022
ISSN: ['2196-7350']
DOI: https://doi.org/10.1002/admi.202201581