Mesophase in melt-spun poly(ϵ-caprolactone) filaments: Structure–mechanical property relationship
نویسندگان
چکیده
منابع مشابه
Mechanical response of melt-spun amorphous filaments
High-speed melt spinning of a cyclo-olefin polymer (COP) and a copolyamide (CoPA) have been performed. Differential scanning calorimetry curves of the resulting monofilaments show that they remain in an amorphous state even after hot drawing. Wide angle x-ray diffraction patterns of undrawn and drawn COP filaments show that although the material remains in an amorphous state, a degree of orient...
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Hysteresis loops of randomly oriented grains with uniaxial anisotropy were computed on the basis of an array of 27 Wigner Seitz cells representing crystallites which interact by exchange coupling at the grain boundaries. The computed coercivity increases linearly with increasing interatomic exchange. Using the experimental anisotropy and exchange parameters for Sm(FellTi), we found 1.lo&=1.2 T ...
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Developing texture in nanocrystalline permanent magnet alloys is of significant importance. Directional annealing is shown to produce texture in the permanent magnet alloy (Sm12Co88)99Nb1. Melt spinning produced isotropic grain structures of the hard magnetic metastable SmCo7 phase, with grain sizes of ∼300 nm. Conventional annealing of melt-spun (Sm12Co88)99Nb1 alloy produced Sm2Co17 phase wit...
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(Fe100-xVx)75P15C10 (x=0, 5, 10 and 15) semiamorphous alloys were prepared by the melt spinning technique and their structural, thermal and magnetic properties were investigated. The structure of the alloys was studied by X-ray diffraction (XRD) for annealing temperatures of 400 oC to 650 oC within a 30 minute annealing time. The XRD patterns show that the samples contain a BCC structure for te...
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T. Bončina, University of Maribor, Faculty of Mechanical Engineering, Maribor, Slovenia The shapes of icosahedral quasicrystalline (IQC) particles were determined in melt-spun ribbons of alloys based on the Al-Mn-Be alloy system. The sizes of the quasicrystalline particles ranged from a few tenths of nanometres up to 1 μm. Therefore, diff erent methods were employed for characterizing their sha...
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ژورنال
عنوان ژورنال: Polymer
سال: 2020
ISSN: 0032-3861
DOI: 10.1016/j.polymer.2020.122870