Missing Linkers: An Alternative Pathway to UiO-66 Electronic Structure Engineering
نویسندگان
چکیده
منابع مشابه
Missing Linkers: An Alternative Pathway to UiO-66 Electronic Structure Engineering
UiO-66 is a promising metal-organic framework for photocatalytic applications. However, the ligand-to-metal charge transfer of an excited electron is inefficient in the pristine material. Herein, we assess the influence of missing linker defects on the electronic structure of UiO-66 and discuss their ability to improve ligand-to-metal charge transfer. Using a new defect classification system, w...
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The recently discovered UiO-66/67/68 class of isostructural metallorganic frameworks (MOFs) [J. H. Cavka et al. J. Am. Chem. Soc., 2008, 130, 13850] has attracted great interest because of its remarkable stability at high temperatures, high pressures and in the presence of different solvents, acids and bases [L. Valenzano et al. Chem. Mater., 2011, 23, 1700]. UiO-66 is obtained by connecting Zr...
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ژورنال
عنوان ژورنال: Chemistry of Materials
سال: 2017
ISSN: 0897-4756,1520-5002
DOI: 10.1021/acs.chemmater.6b05444