Modeling the orientational and positional behavior of polyhedral nanoparticles at fluid-fluid interfaces

Behavior of cells at fluid interfaces.

We have cultured the murine cell lines 3T3-L1 and SV-T2 using as a substrate the layer of denatured protein that forms at the phase boundary between culture medium and fluorocarbon fluids. The growth patterns observed on these interfaces differ from those seen on conventional solid substrates. Depending on the cell strain and the composition of the fluorocarbon fluid, cells will tend to clump i...

The synthesis of nanoparticles and their organization at fluid interfaces

Dynamic Organization of Ligand-Grafted Nanoparticles during Adsorption and Surface Compression at Fluid–Fluid Interfaces

Monolayers of ligand-grafted nanoparticles at fluid interfaces exhibit a complex response to deformation due to an interplay of particle rearrangements within the monolayer, and molecular rearrangements of the ligand brush on the surface of the particles. We use grazing-incidence small-angle X-ray scattering (GISAXS) combined with pendant drop tensiometry to probe in situ the dynamic organizati...

Interactions and stress relaxation in monolayers of soft nanoparticles at fluid-fluid interfaces.

Nanoparticles with grafted layers of ligand molecules behave as soft colloids when they adsorb at fluid-fluid interfaces. The ligand brush can deform and reconfigure, adopting a lens-shaped configuration at the interface. This behavior strongly affects the interactions between soft nanoparticles at fluid-fluid interfaces, which have proven challenging to probe experimentally. We measure the sur...

Solvent-mediated interactions between nanoparticles at fluid interfaces.

We investigate the solvent-mediated interactions between nanoparticles adsorbed at a liquid-vapor interface in comparison to the solvent-mediated interactions in the bulk liquid and vapor phases of a Lennard-Jones solvent. Molecular dynamics simulation data for the latter are in good agreement with results from integral equations in the reference functional approximation and a simple geometric ...