Monoclonal Behavior of Molecularly Imprinted Polymer Nanoparticles in Capillary Electrochromatography
نویسندگان
چکیده
منابع مشابه
Chiral separation of binaphthol enantiomers on molecularly imprinted polymer monolith by capillary electrochromatography.
A novel enantioseparational monolithic stationary phase for binaphthol based on a molecular imprinting method was introduced and evaluated in capillary electrochromatography (CEC). The monolithic stationary was prepared by the in situ copolymerization of methacrylic acid and ethylene glycol dimethacrylate in a porogenic solvent (toluene or toluene-isooctane) in the presence of an imprinting mol...
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Biodegradable polymer nanoparticles are promising carriers for targeted drug delivery in nanomedicine applications. Molecu- lar imprinting is a potential strategy to target polymer nanoparticles through binding of endogenous ligands that may promote recognition and active transport into specific cells and tissues. However, the lock-and-key mechanism of molecular imprinting requires relatively r...
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Two chiral compounds, Tröger's base and tetrahydropalmatine, were enantioseparated on the (5S, 11S)-(-)-Tröger's base and l-tetrahydropalmatine imprinted monolithic capillary columns with CEC, respectively. The monoliths were prepared by in situ thermal-initiated copolymerization of methacrylic acid (MAA) and ethylene dimethacrylate (EDMA). After optimizing the ratio of porogens (toluene and do...
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ژورنال
عنوان ژورنال: Analytical Chemistry
سال: 2008
ISSN: 0003-2700,1520-6882
DOI: 10.1021/ac070038v