Ni2+–Fe3+ cyanometallate structures covalently embedded in silica: Influence of the blocking ligand at Ni2+
نویسندگان
چکیده
منابع مشابه
Covalent Embedding of Ni2+/Fe3+ Cyanometallate Structures in Silica by Sol–Gel Processing
Compound [Ni(AEAPTS)2]3[Fe(CN)6]2 (AEAPTS = N-(2-aminoethyl)-3-aminopropyltrimethoxysilane), in which Ni(2+) and Fe(3+) ions are ferromagnetically coupled through cyano bridges, was prepared. Sol-gel processing of the AEAPTS derivative resulted in incorporation of the cyanometallate in silica. The obtained material is magnetically ordered below 22 K with an effective magnetic moment μeff of 4.4...
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ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 2019
ISSN: 0020-1693
DOI: 10.1016/j.ica.2018.12.019