Nitrosation and Nitration of Olefins using Nitrogen Monoxide.
نویسندگان
چکیده
منابع مشابه
Iron catalysed nitrosation of olefins to oximes.
Fe(BF4)2·6H2O/2,6-pyridinedicarboxylic acid catalysed nitrosation of a wide variety of substituted styrenes has been developed in the presence of t-BuONO/NaBH4 under H2 pressure (10 bar) in MeOH-H2O (5 : 1) to afford corresponding oximes in good to excellent yields.
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Electrophilic aromatic nitrosation and nitration are among the most important electron transfer (ET) reactions. According to the electron transfer theory, an ET process can be described with two electron-localized diabatic states, and the electronic coupling between these two states, together with the organization energy and reaction energy, determine the ET efficiency. A proper definition of t...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1996
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.54.728