One-step preparation of metal-free phthalocyanine with controllable crystal form

نویسندگان

چکیده

Abstract Metal-free phthalocyanine (H 2 Pc) has been widely used as photosensitive semiconductors in the organic optoelectronics field because of its unique planar molecular structure and high photocarriers’ generation efficiency. Herein, this paper related to a new facile efficient one-step method for preparing specific crystal form H Pc with crystallinity through ball-milling process, which α-H can be prepared directly by dry ball-milling, β-H X-H simply obtained wet butanone solvent at different temperatures. X-ray diffraction (XRD) was characterize stability Pc, revealed that all three crystalline had excellent under mechanical conditions.

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ژورنال

عنوان ژورنال: Green Processing and Synthesis

سال: 2021

ISSN: ['2191-9542', '2191-9550']

DOI: https://doi.org/10.1515/gps-2021-0012