Origins of solidification when a simple molecular fluid is confined between two plates

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Origins of solidification when a simple molecular fluid is confined between two plates

A simple globular-shaped liquid ~octamethylcyclotetrasiloxane, OMCTS! was placed between two rigid mica plates at variable spacings comparable to the size of this molecule and the linear shear viscoelasticity of the confined interfacial film was measured. Strong monotonic increase of the shear relaxation time, elastic modulus, and effective viscosity were observed as the spacing was decreased b...

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Glasslike Transition of a Confined Simple Fluid.

A simple globular-shaped liquid (octamethylcyclotetrasiloxane, OMCTS) was placed between two solid plates at variable spacings comparable to the size of this molecule and the linear shear viscoelasticity of the confined interfacial film was measured. Strong monotonic increase of the shear relaxation time, elastic modulus, and effective viscosity were observed at spacings less than about 10 mole...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2001

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.1380207