Phase diagram of selectively cross-linked block copolymers shows chemically microstructured gel
نویسندگان
چکیده
منابع مشابه
Phase diagram of selectively cross-linked block copolymers shows chemically microstructured gel.
We study analytically the intricate phase behavior of cross-linked AB diblock copolymer melts, which can undergo two main phase transitions due to quenched random constraints. Gelation, i.e., spatially random localisation of polymers forming a system-spanning cluster, is driven by increasing the number parameter μ of irreversible, type-selective cross-links between random pairs of A blocks. Sel...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2015
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.4905831