Polymerization by Transition Metal Alkyl and Hydride Complexes
نویسندگان
چکیده
منابع مشابه
Metal Hydrides: Transition Metal Hydride Complexes
Solid-state metal hydrides provide a safe and efficient way of storing hydrogen (Schlapbach 2002). They are commercialized for use in rechargeable batteries and developed for energy conversion devices such as fuel cells (see Hydrogen Metal Systems: Electrochemical Reactions). A great majority of metal hydrides derives from intermetallic compounds and alloys (see Hydrogen Metal Systems: Hydride ...
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a series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization,by coupling the allylated a-diimine complexes of the metals ti, zr, v, ni and pd with the ansa-zirconocenecomplex [c5h4-sih(me)-c5h4]zrcl2 possessing a hydride silane moiety. the different stages of syntheses includedthe formation of bis(cyclopentadienide)methyl silane which was util...
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The data are presented for catalytic H-D exchange of alkanes with protic solvents and some other reactions of alkanes in the presence of transition metal complexes, particularly Pt(II). In Pt(II) chloride solutions the activity of Pt-containing species towards alkanes is in the order S2PtC12> SPtC13> PtC14 (S—solvent). Ligands with properties of soft bases (CN, CNS, PPh etc.) decrease the rate ...
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ژورنال
عنوان ژورنال: Kobunshi
سال: 1970
ISSN: 0454-1138,2185-9825
DOI: 10.1295/kobunshi.19.765