Quantitative size-dependent structure and strain determination of CdSe nanoparticles using atomic pair distribution function analysis

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Quantitative size-dependent structure and strain determination of CdSe nanoparticles using atomic pair distribution function analysis

The size-dependent structure of CdSe nanoparticles, with diameters ranging from 2 to 4 nm, has been studied using the atomic pair distribution function PDF method. The core structure of the measured CdSe nanoparticles can be described in terms of the wurtzite atomic structure with extensive stacking faults. The density of faults in the nanoparticles is 50%. The diameter of the core region was e...

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Confirmation of disordered structure of ultrasmall CdSe nanoparticles from X-ray atomic pair distribution function analysis.

The atomic pair distribution function (PDF) analysis of X-ray powder diffraction data has been used to study the structure of small and ultra-small CdSe nanoparticles. A method is described that uses a wurtzite and zinc-blende mixed phase model to account for stacking faults in CdSe particles. The mixed-phase model successfully describes the structure of nanoparticles larger than 2 nm yielding ...

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ژورنال

عنوان ژورنال: Physical Review B

سال: 2007

ISSN: 1098-0121,1550-235X

DOI: 10.1103/physrevb.76.115413