Reaction path of the oxidative coupling of methane over a lithium-doped magnesium oxide catalyst
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چکیده
منابع مشابه
The oxidative coupling of methane and the oxidative dehydrogenation of ethane over a niobium promoted lithium doped magnesium oxide catalyst
The promoting effect of niobium in a Li/MgO catalyst for the oxidative coupling of methane (OCM) and for the oxidattve dehydrogenation of ethane (ODHE) has been studied in some detail. it has been found that a Li/Nb/MgO catalyst with 16 wt % niobium showed the highest activity for the C, production in the OCM reaction; the activity at 600 “C was ten times that of the Li/MgO catalyst at the same...
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Active sites are created on the surface of a Li/MgO catalyst used for the selective oxidation of methane by the gradual loss of carbondioxide from surface carbonate species in the presence of oxygen. Decomposition of the carbonat~ species in the absence of oxygen is detrimental to the activity of the cataIy~t. The active sites'created are not stable but disappear either as a result of reaction ...
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It has been found that it is possible to improve the activity and stability for the oxidative coupling of methane of a Li/MgO catalyst by the addition of small amounts of the oxides of various transition and rare earth metals. A number of these additives, e.g. SnOZ, TiOz, Dy,O, and Tb407, caused little or no difference in the selectivity to C, products achieved with the resultant catalyst while...
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We present a study on the catalytic cycle responsible for coupling of methane by molecular oxygen over a lithium-doped magnesium oxide catalyst. To elucidate the mechanism by which methyl radicals are produced and the active sites are regenerated, geometries and energies of relevant reaction intermediates were determined using an ab initio embedded cluster model. Our results suggest a new mecha...
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In this article, the effect of operating conditions, such as temperature, Gas Hourly Space Velocity (GHSV), CH4/O2 ratio and diluents gas (mol% N2) on ethylene production by Oxidative Coupling of Methane (OCM) in a fixed bed reactor at atmospheric pressure was studied over Mn/Na2WO4/SiO2 ca...
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ژورنال
عنوان ژورنال: Applied Catalysis
سال: 1989
ISSN: 0166-9834
DOI: 10.1016/s0166-9834(00)83378-3