Reactions of Carbanions with Triplet and Singlet Molecular Oxygen
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چکیده
منابع مشابه
Reactions of carbanions with triplet and singlet molecular oxygen.
The gas phase reactions of carbanions with molecular oxygen in both its ground state (X3 sigma g-) and first electronically excited state (a1 delta g) have been studied by the flowing afterglow technique. Reactions include cleavage processes, charge transfer, hydride transfer, formation of hydroxide ion and processes which involve secondary reactions within a long-lived complex. The mechanisms ...
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Pterins, derivatives of 2-aminopteridin-4(3H)-one, are natural photosensitizers, common to many biological systems. Indications that these photosensitizers are also present in the sea-surface microlayer motivated the study of the photophysical and photochemical properties of 6-carboxypterin (CPT), which was chosen as a model for this group of photoactive compounds. The kinetics of excited CPT i...
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ژورنال
عنوان ژورنال: Environmental Health Perspectives
سال: 1980
ISSN: 0091-6765
DOI: 10.2307/3429340