Regulating carbon work function to boost electrocatalytic activity for the oxygen reduction reaction

نویسندگان

چکیده

Electronic regulation of carbon is essential for developing non-platinum electrocatalysts oxygen reduction reactions (ORRs). In this work, we used Cs to further regulate the electronic structure nitrogen-doped (N-doped) carbon. The atoms coordinated with nitrogen atom in N-doped injecting electrons into conjugate and reducing work function network. low-work-function surface improved electron donation, facilitated O2 dissociation, enhanced adsorption an OOH* intermediate. Thus, electrocatalytic performance ORR was improved. material shows potential as electrocatalyst comparable Pt/C.

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ژورنال

عنوان ژورنال: Chinese Journal of Catalysis

سال: 2021

ISSN: ['0253-9837', '1872-2067']

DOI: https://doi.org/10.1016/s1872-2067(20)63701-9