Restricted Speciation and Supramolecular Assembly in the 5f Block
نویسندگان
چکیده
منابع مشابه
Solvent-dependent self-assembly behaviour and speciation control of Pd6L8 metallo-supramolecular cages.
The C3-symmetric chiral propylated host-type ligands (±)-tris(isonicotinoyl)-tris(propyl)-cyclotricatechylene (L1) and (±)-tris(4-pyridyl-4-benzoxy)-tris(propyl)-cyclotricatechylene (L2) self-assemble with Pd(II) into [Pd6L8](12+) metallo-cages that resemble a stella octangula. The self-assembly of the [Pd6(L1)8](12+) cage is solvent-dependent; broad NMR resonances and a disordered crystal stru...
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ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2018
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.201801044