Retention of Water in Terrestrial Magma Oceans and Carbon-rich Early Atmospheres
نویسندگان
چکیده
Abstract Massive steam and CO 2 atmospheres have been proposed for magma ocean outgassing of Earth terrestrial planets. Yet formation such depends on volatile exchange with the molten interior, governed by solubilities redox reactions. We determine evolution ocean–atmosphere systems a range oxygen fugacities, C/H ratios, hydrogen budgets that include reactions (H –H O), carbon (CO–CO ), methane (CH 4 solubility laws H O . find small initial hydrogen, high oxidizing conditions suppress until late stage crystallization. Hence, early in equilibrium oceans are dominantly carbon-rich, specifically CO-rich except at most conditions. The limits its to melt fractions below ∼30%, fraction which mantle transitions from vigorous sluggish convection percolation. Sluggish percolation could enable surface lid form, trapping water interior thereby maintaining carbon-rich atmosphere (equilibrium crystallization). Alternatively, efficient crystal settling maintain surface, promoting transition water-rich (fractional However, additional processes, including dissolution crystallizing minerals, further conspire limit extent outgassing, even fractional much delivered planets during their accretion can be safely harbored interiors stage, particularly
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ژورنال
عنوان ژورنال: The planetary science journal
سال: 2022
ISSN: ['2632-3338']
DOI: https://doi.org/10.3847/psj/ac5fb1