Robust Core–Shell Carbon-Coated Silicon-Based Composite Anode with Electrically Interconnected Spherical Framework for Lithium-Ion Battery

نویسندگان

چکیده

Carbon-coated Si/carbon nanotube/graphene oxide (C-Si/CNT/GO) microspheres with a robust core–shell composite structure were successfully fabricated by efficient and scalable spray-drying chemical vapor deposition (CVD) for application as lithium-ion battery (LIB) anode. The amphiphilic GO nanoparticles facilitated the uniform dispersion of Si suppressing CNT aggregation in Si/CNT/GO microspheres, efficiently forming microsphere structure. surface was coated carbon using CH4 via CVD to enhance its cycling performance. four building block components, namely, nanoparticles, CNTs, core carbon-coating layers shell, provided high electrochemical capacity, excellent electrical conductivity, buffer space volume expansion structural stability during lithiation/delithiation. C-Si/CNT/GO anode also exhibited performance specific capacity (2921 mAh g–1 at 100 mA g–1), long cycle life (1542 200 after cycles), charge/discharge rate (1506 6 A g–1). This approach fabricating structured Si-based anodes will provide significant breakthrough developing next-generation LIBs.

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ژورنال

عنوان ژورنال: International Journal of Energy Research

سال: 2023

ISSN: ['0363-907X', '1099-114X']

DOI: https://doi.org/10.1155/2023/6874429