Sampled-Current Voltammetry at Microdisk Electrodes: Kinetic Information from Pseudo Steady State Voltammograms
نویسندگان
چکیده
منابع مشابه
Evaluation technique of kinetic parameters for irreversible charge transfer reactions from steady-state voltammograms at microdisk electrodes
An explicit approximate expression for half-wave potentials of irreversible steady-state current-voltage curves at a microdisk electrode was derived from the diffusion equation and the Butler-Volmer equation on the basis of the previous analytical method (J. E. C., 235 (1987) 87). The plot of the half-wave potential, E1/2, against ln(1-exp(-(E1/2E))F/RT)] showed a linear relation with the slope...
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ژورنال
عنوان ژورنال: Analytical Chemistry
سال: 2014
ISSN: 0003-2700,1520-6882
DOI: 10.1021/ac502645e