Simultaneous Detection of Monoethanolamine, Diethanolamine, and Triethanolamine by HPLC with a Chemiluminescence Reaction and Online Derivatization to Tertiary Amine

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Simultaneous detection of monoethanolamine, diethanolamine, and triethanolamine by HPLC with a chemiluminescence reaction and online derivatization to tertiary amine.

In this paper we propose a new postcolumn detection method for compounds having primary, secondary, and tertiary amine moieties. The primary and secondary amine are delivatized by a reaction with epichlorohydrin having an epoxy moiety in a reaction coil to yield a tertiary amine with subsequent chemiluminescence detection using [Ru(bpy)3]3+. The liner values of the calibration curves of monoeth...

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ژورنال

عنوان ژورنال: Analytical Sciences

سال: 2005

ISSN: 0910-6340,1348-2246

DOI: 10.2116/analsci.21.497