Spectrophotometric determination of chromium (VI) with ο-hydroxyhydroquinonephthalein and cationic surface-active agent
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Catalytic Spectrophotometric Determination of Chromium
chromium(III) up to 100 ng mL−1, and for chromium(VI) up to 200 ng mL−1) were obtained, using the “fixed time” method with detection limits of 4.9 ng mL−1 and 3.8 ng mL−1, respectively. The results suggest that at the reaction conditions chromium(VI) is reduced and chromium(III) is oxidized to an intermediate oxidation state and the catalytic action of chromium is due to the formation of an act...
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Simultaneous and fractional determination of iron(II) and iron(III) was accomplished with o-hydroxyhydroquinonephthalein (QP) in the presence of poly (N-vinyl pyrrolidone). In the determination of total iron (iron(II)+iron(III)), Beer's law was obeyed in the range of 0.02-0.67 μg·ml(-1), with an effective molar absorptivity (at 570 nm) and a relative standard deviation of 1.30×10(5)·l·mol(-1)·c...
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A simple and highly sensitive spectrophotometric method for the determination of glucosamine and its analogous amino sugars was established based on fading of the palladium(II)-o-hydroxyhydroquinonephthalein-hexadecyltrimethylammonium complex. In the determination of glucosamine, Beer's law is obeyed in the range of 0.02 - 0.18 microg ml(-1), with an effective molar absorptivity at 630 nm and t...
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A spectrophotometric method employing 2-hydroxybenzaldiminoglycine (HBIG) is proposed for the determination of chromium(III). The results of the determinations are compared with the standard diphenyl carbazide method. The presently developed method is direct, simple, rapid, selective, sensitive and precise. DOI: 10.1134/S106193480601@@@@
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1979
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.28.11_707