Spin-torsion effects in the hyperfine structure of methanol

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Spin-torsion effects in the hyperfine structure of methanol.

The magnetic hyperfine structure of the non-rigid methanol molecule is investigated experimentally and theoretically. 12 hyperfine patterns are recorded using molecular beam microwave spectrometers. These patterns, along with previously recorded ones, are analyzed in an attempt to evidence the effects of the magnetic spin-torsion coupling due to the large amplitude internal rotation of the meth...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2015

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.4926942