Stability of Lanthanum Cobaltite and Rare Earth Substituted Ceria Interface

Structural and Thermoelectric Properties of Rare-Earth-Substituted Sr3Fe2O7

The structural and thermoelectric properties of rare-earth (Sm)-substituted Ruddlesden­Popper-type Sr3Fe2O7, Sr31xSmxFe2O7 (SSFO, x = 0, 0.1, 0.15), were investigated by measuring the temperature dependence of its crystallographic parameters, electrical conductivity, and Seebeck coefficient (S). A sharp increase in electrical conductivity (·) up to 60 S/cm (log · = 1.78 S/cm) at 400­500°C occur...

Combustion and Ball Milled Synthesis of Rare Earth Nano-Sized Ceria Powder

This paper reports a study on nanocrystalline ceria powder prepared by high energy ball-milling and combustion synthesis methods. The combustion synthesis was carried out using ceric ammonium nitrate as oxidizer and citric acid, glycine or citric acid plus glycine as fuel. The minimum crystallite size of ceria powder is obtained by combustion synthesis of ceric ammonium nitrate and citric acid....

A combined DFT + U and Monte Carlo study on rare earth doped ceria.

We investigate the dopant distribution and its influence on the oxygen ion conductivity of ceria doped with rare earth oxides by combining density functional theory and Monte Carlo simulations. We calculate the association energies of dopant pairs, oxygen vacancy pairs and between dopant ions and oxygen vacancies by means of DFT + U including finite size corrections. The cation coordination num...

Stability and Decomposition of Ca-Substituted Lanthanum Ferrite in Reducing Atmospheres

Ethyl Acetate Abatement on Copper Catalysts Supported on Ceria Doped with Rare Earth Oxides.

Different lanthanide (Ln)-doped cerium oxides (Ce0.5Ln0.5O1.75, where Ln: Gd, La, Pr, Nd, Sm) were loaded with Cu (20 wt. %) and used as catalysts for the oxidation of ethyl acetate (EtOAc), a common volatile organic compound (VOC). For comparison, both Cu-free (Ce-Ln) and supported Cu (Cu/Ce-Ln) samples were characterized by N₂ adsorption at -196 °C, scanning/transmission electron microscopy, ...