Strain-modulated piezoelectric and electrostrictive nonlinearity in ferroelectric thin films without active ferroelastic domain walls

Ferroelastic domains in bilayered ferroelectric thin films

We investigate theoretically ferroelastic domain fractions in a heteroepitaxial bilayer consisting of 001 tetragonal PbZrxTi1−xO3 and 001 rhombohedral PbZr1−xTixO3 on a thick 001 passive substrate as a function of the lattice misfit strain between layers and the substrate. By considering the self-strain in each layer and the indirect elastic interaction between the layers, we provide a numerica...

Depletion layers and domain walls in semiconducting ferroelectric thin films.

Commonly used ferroelectric perovskites are also wide-band-gap semiconductors. In such materials, the polarization and the space-charge distribution are intimately coupled, and this Letter studies them simultaneously with no a priori ansatz on either. In particular, we study the structure of domain walls and the depletion layers that form at the metal-ferroelectric interfaces. We find the coupl...

Microwave a.c. conductivity of domain walls in ferroelectric thin films

Ferroelectric domain walls are of great interest as elementary building blocks for future electronic devices due to their intrinsic few-nanometre width, multifunctional properties and field-controlled topology. To realize the electronic functions, domain walls are required to be electrically conducting and addressable non-destructively. However, these properties have been elusive because conduc...

Ferroelectric and ferroelastic domain wall motion in unconstrained Pb(Zr,Ti)O3 microtubes and thin films.

Ferroelectric polarization switching of high aspect ratio (>80:1) PbZr(0.52)Ti(0.48)O(3) (PZT) microtubes with a wall thickness of ~200 nm was investigated. A charge-based technique was used to assess the dielectric and ferroelectric properties of individual mechanically-unconstrained PZT microtubes with interdigitated electrodes. An enhancement in the degree of ferroelastic (non-180 degrees ) ...

Thickness-dependent evolutions of domain configuration and size in ferroelectric and ferroelectric-ferroelastic films