Structural transformation of Pd-α-Fe2O3 and Pd-γ-Fe2O3 catalysts and application in the CO oxidation reaction
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چکیده
منابع مشابه
Structural behavior of laser-irradiated γ-Fe2O3 nanocrystals dispersed in porous silica matrix : γ-Fe2O3 to α-Fe2O3 phase transition and formation of ε-Fe2O3
The effects of laser irradiation on γ-Fe2O3 4 ± 1 nm diameter maghemite nanocrystals synthesized by co-precipitation and dispersed into an amorphous silica matrix by sol-gel methods have been investigated as function of iron oxide mass fraction. The structural properties of γ-Fe2O3 phase were carefully examined by X-ray diffraction and transmission electron microscopy. It has been shown that γ-...
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Nano crystals of γ-Fe2O3 (maghemite) were synthesized by emulsion precipitation method using kerosene as oil phase, SPAN80 (sorbitane monooleate) as the surfactant and sodium hydroxide as the precipitating agent. The characterization of the samples by FTIR (Fourier transform infra-red) and XRD (X-ray diffraction) techniques confirmed the formation of γ-Fe2O3 (maghemite). Analysis by SEM (scanni...
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Facile synthesis of Pd-based bimetallic nanocrystals and their application as catalysts for methanol oxidation reaction.
We employed an efficient and facile route to synthesise monodisperse Pd-based bimetallic nanocrystals (MPd: M = Cu, Co and Ni) via a controlled co-reduction of Pd(ii) chloride and M(ii) nitrate at 200-230 °C in the presence of oleylamine (OAm). These monodisperse Pd-based nanocrystals have small dimensions, unique structures and homogeneous morphology, thus exhibit efficient catalytic activitie...
متن کاملA Theoretical Investigation on CO Oxidation by Single‐Atom Catalysts M1/γ‐Al2O3 (M=Pd, Fe, Co, and Ni)
Single-atom catalysts have attracted much interest recently because of their excellent stability, high catalytic activity, and remarkable atom efficiency. Inspired by the recent experimental discovery of a highly efficient single-atom catalyst Pd1/γ-Al2O3, we conducted a comprehensive DFT study on geometries, stabilities and CO oxidation catalytic activities of M1/γ-Al2O3 (M=Pd, Fe, Co, and Ni)...
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ژورنال
عنوان ژورنال: RSC Advances
سال: 2017
ISSN: 2046-2069
DOI: 10.1039/c7ra09580e