Studies on Fluorene Derivatives. IV-V.V. 2, 2, -Dibromo-7, 7'-dichloro-bisdiphenylene-ethylene.
نویسندگان
چکیده
منابع مشابه
2′,7′-Dibromospiro[cyclopropane-1,9′-fluorene]
In the title compound, C15H10Br2, each mol-ecule is situated on special postion mm, so the asymmetric unit contains one-quater of a mol-ecule. The 2,7-di-bromo-9H-fluorene fragment and three spiro-cyclo-propane C atoms lie on different planes, which are perpendicular to each other. In the crystal, π-π inter-actions between aromatic rings [inter-centroid distance = 3.699 (3) Å] pack the mol-ecul...
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In title compound, C(12)H(11)Br(2)NO(2), the coumarin ring system is almost planar, the two rings being inclined to one another by 1.40 (15)°. There are two short intra-molecular inter-actions (N-H⋯Br and C-H⋯Br) involving the Br atoms. In the crystal, mol-ecules stack along the a-axis direction via π-π inter-actions; the centroid-centroid distances vary from 3.6484 (19) to 3.7942 (19) Å.
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1954
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.75.714