Studies on polyfunctional cyclophosphazene monomers for dental use. (I). Synthesis of monomers and physical properties of monomers.

Studies on polyfunctional cyclophosphazene monomers for dental use (2)--physical properties of polymers.

The present studies were aimed at the development of monomers for dental resins, for which the authors substituted the 8 Cl atoms in P4N4Cl8 with hydrophobic groups (Ph, TF and OF) and a polymerizing group (EMA), and bulk-polymerized them in order to examine their physical properties. Attention was focused on the relationship between the number of substituted hydrophobic groups and the mechanic...

Antimicrobial Monomers for Polymeric Dental Restoratives: Cytotoxicity and Physicochemical Properties

A trend for the next generation of polymeric dental restoratives is to incorporate multifunctional capabilities to regulate microbial growth and remineralize tooth surfaces. Polymerizable 2-(methacryloyloxy)-N-(2-(methacryloyloxy)ethyl)-N,N-dimethylethan-1-aminium bromide (IDMA1) and N,N'-([1,1'-biphenyl]-2,2'-diylbis(methylene))bis(2-(methacryloyloxy)-N,N-dimethylethan-1-aminium) bromide (IDMA...

Polyelectrolyte properties of proteoglycan monomers

DFT studies of all fluorothiophenes and their radical cations as candidate monomers for conductive polymers

In this paper, electronic, structural, and spectroscopic properties of mono-, di-, tri-, andtetrafluorothiophenes and their radical cations are studied using the density functional theory andB3LYP method with 6-311++G** basis set. Also the effects of the number and position of thesubstituent on the electrochemical properties of the thiophene ring have been studied usingoptimized structures obta...

Study the curing behavior and mechanical properties of Pigmented UV curable epoxy acrylate monomers

The formulations contained different acrylate monomer with different structure and functionalities and TiO2, were applied to obtain pigmented acrylic films by UV exposure. The conversion and mechanical characteristic were correlated. The results showed that there is a significant interaction between pigment, reactive diluents’ type and mechanical properties of coatings. It seems that cured film...