Surfactant flooding for enhanced oil recovery – Insights on oil solubilization through optical spectroscopic approach

نویسندگان

چکیده

Surfactant flooding is a proven method employed to improve the recovery of crude oil from subsurface reservoirs but knowledge about microemulsion formation, factors related their stability, and trapping mechanism components in still not clear for designing injection fluid specific type. The interaction mechanisms four oils with surfactant-brine solutions were studied this work better insight into molecular level during surfactant flooding. UV–visible absorption fluorescence spectra separated maltene asphaltene fractions indicate structural difference level, particularly, size fused aromatic rings (FAR) present within individual bulk sample. Moreover, FTIR asphaltenes samples clearly showed subtle functional groups respective FAR structures. Well-characterized compositionally different mixed (anionic – SDS, AOS, cationic - CTAB, neutral TX-100) examined using spectroscopic approach. Detailed analysis acquired oil-surfactant-brine distinctly demonstrate entrapment micelles formed by surfactants charges while synchronous show FARs micellar microenvironment. results exhibit that anionic entraps smaller (2–4) whereas entrap small as well medium (2–6) microemulsions. study signifies importance molecular-level customized maximizing petroleum reservoirs.

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ژورنال

عنوان ژورنال: Journal of Petroleum Science and Engineering

سال: 2022

ISSN: ['0920-4105', '1873-4715']

DOI: https://doi.org/10.1016/j.petrol.2021.109803