Synthesis of 6-Trimethylsilyl-α-pyrone from 2,6-Bis(trimethylsilyl)- pyran via Mild Aerobic Oxidation
نویسندگان
چکیده
منابع مشابه
Synthesis of α,β-unsaturated carbonyl compounds via a visible-light-promoted organocatalytic aerobic oxidation.
α,β-Unsaturated ketones and aldehydes have been synthesized from their corresponding silyl enol ethers in a straightforward protocol involving a visible-light promoted organocatalytic, aerobic oxidation reaction. A cheap organic dye was used catalytically in these reactions as the photosensitizer.
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A new α-pyrone derivative 1, along with four known congeners 2, 3, 4 and 5, were isolated from the solid-substrate fermentation medium of the endophytic fungus Pestalotiopsis microspore isolated from the branch of Taxus chinensis. Their structures and relative configurations were elucidated by extensive spectroscopic analysis. The cytotoxic activities of the isolated α-pyrone derivatives agains...
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15 صفحه اولProduction of 6-pentyl-α-pyrone by trichoderma harzianum in solid-state fermentation
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ژورنال
عنوان ژورنال: Chinese Journal of Organic Chemistry
سال: 2013
ISSN: 0253-2786
DOI: 10.6023/cjoc201209027