Synthesis of cadmium sulphide in pure and mixed Langmuir-Blodgett films ofn-octadecylsuccinic acid
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The structure of ultrathin Langmuir-Blodgett films of cadmium behenate.
Grazing incidence x-ray-diffraction investigations of the structures of Langmuir-Blodgett films of cadmium behenate with 1, 2, 3, 5, and 21 monolayers are reported. The single monolayer film, deposited on a hydrophilic substrate, showed a hexagonal structure, whereas the bilayer film, deposited on a hydrophobic substrate, had a rectangular structure with herringbone orientation of the acyl chai...
متن کاملRole of microenvironment in the mixed Langmuir-Blodgett films.
This paper reports the pi-A isotherms and spectroscopic characteristics of mixed Langmuir and Langmuir-Blodgett (LB) films of nonamphiphilic carbazole (CA) molecules mixed with polymethyl methacrylate (PMMA) and stearic acid (SA). pi-A isotherm studies of mixed monolayer as well as the remarkable change in collapse pressure of the mixed monolayer isotherms definitely show that CA is incorporate...
متن کاملStable ordering in Langmuir-Blodgett films.
Defects in the layering of Langmuir-Blodgett (LB) films can be eliminated by depositing from the appropriate monolayer phase at the air-water interface. LB films deposited from the hexagonal phase of cadmium arachidate (CdA2) at pH 7 spontaneously transform into the bulk soap structure, a centrosymmetric bilayer with an orthorhombic herringbone packing. A large wavelength folding mechanism acce...
متن کاملPhotoinduced Electron Transfer in Langmuir-blodgett Films
Photoinduced electron transfer from an excited donor molecule (oxacyanine) to an acceptor molecule (viologen) located at the same interface in monolayer assemblies has been studied by measuring steady state fluorescence quenching and the excited state decay of the donor molecule. Donor and acceptor molecules are incorporated in matrix monolayers of arachidic acid and methyl arachidate, with a m...
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ژورنال
عنوان ژورنال: Journal of Chemical Sciences
سال: 2000
ISSN: 0253-4134,0973-7103
DOI: 10.1007/bf02704312