Synthesis, structure and properties of V(V) monooxido complex with ONO tridentate Schiff base
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چکیده
منابع مشابه
Template Synthesis, Structural Characterization and Antibacterial Activity of an Unsymmetrical Tridentate Schiff Base Nickel(II) Complex
Nickel(II) complex of [NiL2](ClO4)2, where L is an unsymmetrical tridentate ligand of 2-(2-aminoethyl)imino-3-butanone oximehas been synthesized by a template condensation reaction. The complex was characterized on the basis of microanalytical, spectroscopic, and other physicochemical properties. X-ray diffraction study of the complex revea...
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A novel dioxidomolybdenum complex, [MoO(2)L], derived from the tridentate aroylhydrazone 2-amino-N'-(2-hydroxy-3-methylbenzylidene)benzohydrazide (H(2)L), has been prepared and characterized by elemental analysis, FT-IR, (1)H NMR, and single crystal structural X-ray diffraction. The complex has distorted square pyramidal structure in which the aroylhydrazone ligand behaves as a binegative donor...
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The tridentate ONO-donor Schiff base ligand H2L, derived from the condensation of 1-anisyl-1,3-butanedione and 2-aminophenol, was generated in situ and reacted with Cu(NO3)2•3H2O to yield two doubly phenoxo bridged di-copper(II) complexes depending on the nitrogenous base used. [Cu2L2] (1) is obtained in 85% and 75% yield in the presence of pyridine or 4-picoline, respectively, and [(py-tBu)2Cu...
متن کاملSynthesis, X-ray structure and DFT calculation of oxido-vanadium(V) complex with a tridentate Schiff base ligand
Reaction of 4-bromo-2-(((5-chloro-2-hydroxyphenyl) imino)methyl) phenol (H2L) with VOSO4 XH2O generates the oxido-vanadium(V) complex [VOL(OCH3)(OHCH3)], that characterized by FT-IR, UV–Vis, and elemental analysis. The complex was also characterized by single crystal X-ray diffraction crystallography. A DFT calculation was carried out on the complex using the B3LYP/ 6-31?G(d,p)method. The agree...
متن کاملtemplate synthesis, structural characterization and antibacterial activity of an unsymmetrical tridentate schiff base nickel(ii) complex
nickel(ii) complex of [nil2](clo4)2, where l is an unsymmetrical tridentate ligand of 2-(2-aminoethyl)imino-3-butanone oximehas been synthesized by a template condensation reaction. the complex was characterized on the basis of microanalytical, spectroscopic, and other physicochemical properties. x-ray diffraction study of the complex reveals nickel(ii) center in a distorted octahedral environm...
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ژورنال
عنوان ژورنال: Science, Technology and Innovation
سال: 2019
ISSN: 2544-9125
DOI: 10.5604/01.3001.0013.1046