[Tc(NO)Cl(Cp)(PPh <sub>3</sub> )] – A Technetium(I) Compound with an Unexpected Synthetic Potential
نویسندگان
چکیده
Stable technetium(I) complex cations with Fischer-type carbene ligands are formed during reactions of [Tc(NO)(Cp)Cl(PPh3)] trimetylsilyl propyne and Ag(PF6) in CH2Cl2/-alcohol mixtures, while the dimeric compound [{Tc(NO)(Cp)(PPh3)}2Cl]+ is formed, when no other ligand provided.
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2021
ISSN: ['1434-1948', '1099-0682']
DOI: https://doi.org/10.1002/ejic.202100521