The Base-catalyzed Oxidation of Friedelin with Molecular Oxygen
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چکیده
منابع مشابه
Oxidation of benzylic alcohols with molecular oxygen catalyzed by Cu3/2[PMo12O40]/SiO2
The aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using Cu3/2[PMo12O40]/SiO2 as catalyst under mild reaction condition. This reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.
متن کاملOxidation of benzylic alcohols with molecular oxygen catalyzed by Cu3/2[PMo12O40]/SiO2
The aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using Cu3/2[PMo12O40]/SiO2 as catalyst under mild reaction condition. This reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.
متن کاملBase metal-catalyzed benzylic oxidation of (aryl)(heteroaryl)methanes with molecular oxygen
The methylene group of various substituted 2- and 4-benzylpyridines, benzyldiazines and benzyl(iso)quinolines was successfully oxidized to the corresponding benzylic ketones using a copper or iron catalyst and molecular oxygen as the stoichiometric oxidant. Application of the protocol in API synthesis is exemplified by the alternative synthesis of a precursor to the antimalarial drug Mefloquine...
متن کاملoxidation of benzylic alcohols with molecular oxygen catalyzed by cu3/2[pmo12o40]/sio2
the aerobic oxidation of alcohols was efficiently completed in high conversion and selectivity using cu3/2[pmo12o40]/sio2 as catalyst under mild reaction condition. this reaction provides a new environmentally friendly rout to the conversion of alcoholic function to carbonyl groups.
متن کاملCuO and Ag2O/CuO catalyzed oxidation of aldehydes to the corresponding carboxylic acids by molecular oxygen.
Furfural was oxidized to furoic acid by molecular oxygen under catalysis by 150 nm-sized Ag(2)O/CuO (92%) or simply CuO (86.6%). When 30 nm-size catalyst was used,the main product was a furfural Diels-Alder adduct. Detailed reaction conditions and regeneration of catalysts were investigated. Under optimal conditions, a series of aromatic and aliphatic aldehydes were oxidized to the correspondin...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1966
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.39.200