The intersystem crossing of a cyclic (alkyl)(amino) carbene gold (i) complex
نویسندگان
چکیده
منابع مشابه
Ligand Exchange at a Gold(I) Carbene Complex
Dedicated to Professor Heinrich Nöth on the occasion of his 85th birthday Gold complex [AuCl(NHC)] (NHC = N,N′-dipropylbenzimidazolin-2-ylidene) 1 undergoes facile substitution reactions at the gold(I) center. Treatment of 1 with anionic phenylacetylide or thiophenolate led to the neutral gold complexes 2 and 3, respectively. The cationic gold complexes [Au(NHC)(pyridine)](BF4) [4]BF4 and [Au2(...
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The observed exponential phosphorescence decay of pyrazlne In cyclohexane or benzene matrix at 77K, with lifetime of 18 millisec, is found to change into a complex decay below 10'%:. At 1.6K, the decay is resolved Into three first-order decays of lifetimes 6, 130 and 400 millisec. These lifetimes are sensitive to changes in temperature and magnetic field strength (Hall, Armstrong, Moomaw and El...
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ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2018
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.5032185