The surface catalytic mechanism: a comparative study with square-wave and staircase cyclic voltammetry
نویسندگان
چکیده
منابع مشابه
Surface Catalytic Mechanism in Square-Wave Voltammetry
A pseudo-first-order catalytic mechanism in which both reactant and product of the redox reaction are strongly immobilized on the electrode surface is theoretically analyzed under conditions of square-wave voltammetry (SWV). A mathematical procedure is developed for diffusionless conditions. The relationships between the properties of the voltammetric response and both the kinetic parameters of...
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Square-wave voltammetry of surface redox reactions is considered as an adequate model for a protein-film voltammetric setup. Here we develop a theoretical approach to analyze the effects of temperature on square-wave voltammograms. The performed simulations address the surface redox reactions featuring slow, modest and fast electron transfer. The theoretical calculations show that the temperatu...
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ژورنال
عنوان ژورنال: Journal of Solid State Electrochemistry
سال: 2003
ISSN: 1432-8488
DOI: 10.1007/s10008-002-0290-7