The Weyl Semimetals <i>M</i>IrTe<sub>4</sub> (M = Nb, Ta) as Efficient Catalysts for Dye‐Sensitized Hydrogen Evolution

نویسندگان

چکیده

The prevalent global energy crisis calls for searching viable pathways generating green hydrogen as an alternative resource. Dye-sensitized photocatalytic water splitting is a feasible solution to produce hydrogen. However, identifying suitable catalysts has been one of the bottlenecks in driving dye-sensitized photocatalysis efficiently. In this work, new class electrocatalysts reported based on layered Weyl semimetals MIrTe4 (M = Nb, Ta) Eosin Y (EY)-sensitized evolution reaction (HER). NbIrTe4 and TaIrTe4 exhibit HER activities ≈18 000 14 µmol g−1 respectively, after 10 h irradiation with visible light. Time-dependent UV-Vis spectroscopy high-pressure liquid chromatography coupled mass spectrometry analysis shed light dynamics enable deeper understanding observed trend rates MIrTe4. outperform transition metal-based terms catalytic activity using EY photosensitizer triethanolamine sacrificial agent. It hypothesized that topology-related band inversion promotes high density M d-states near Fermi level, their performance. This study introduces efficient catalysts, provides perspectives designing topology-enhanced catalysts.

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ژورنال

عنوان ژورنال: Advanced Energy Materials

سال: 2023

ISSN: ['1614-6832', '1614-6840']

DOI: https://doi.org/10.1002/aenm.202300503