Theory of Anodic Stripping Voltammetry at Wall-Jet Electrodes. Simulation of Spatially Differential Stripping and Redeposition Phenomena

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Theory of Anodic Stripping Voltammetry at Wall-Jet Electrodes. Simulation of Spatially Differential Stripping and Redeposition Phenomena

Numerical simulations based on the time dependent backward implicit method are used to develop the theory of anodic stripping voltammetry carried out under hydrodynamic conditions using mercury thin film wall-jet electrodes. The peak shape is shown to be highly sensitive both to electrolyte flow rate and to the potential sweep rate. The simulations permit visualization of concentrations both in...

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ژورنال

عنوان ژورنال: The Journal of Physical Chemistry B

سال: 1998

ISSN: 1520-6106,1520-5207

DOI: 10.1021/jp9720810