Thermodynamic Properties of Ethanol + Pyridine, Ethanol + Benzene, and Pyridine + Benzene Mixtures at Temperature 298.15 K and Under Atmospheric Pressure

نویسندگان

چکیده

Experimental densities, viscosities, refractive indices, and sound speeds at temperature 298.15 K atmospheric pressure are reported for the binary liquid mixtures of ethanol + benzene, pyridine, benzene pyridine. From these experimental data, various thermodynamic excess deviation properties were calculated fitted by Redlich-Kister polynomial to determine adjustable coefficients standard deviations. The number significantly representing each property was optimized applying F-test. variation with composition has been interpreted in terms molecular interactions between components mixture structural effects. Furthermore, several theoretical semi-empirical models used predict indices investigated mixtures. predicting ability model ascertained mean absolute percentage data.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Mutual diffusion of binary liquid mixtures containing methanol, ethanol, acetone, benzene, cyclohexane, toluene, and carbon tetrachloride.

Mutual diffusion coefficients of all 20 binary liquid mixtures that can be formed out of methanol, ethanol, acetone, benzene, cyclohexane, toluene, and carbon tetrachloride without a miscibility gap are studied at ambient conditions of temperature and pressure in the entire composition range. The considered mixtures show a varying mixing behavior from almost ideal to strongly non-ideal. Predict...

متن کامل

Preferential Solvation of Fenofibrate in (Ethanol or Acetone) + Water Mixtures at 298.15 K

The aim of this communication was to expand the results of numerical analyses performed by Sun et al. on their experimental solubility of fenofibrate in aqueous mixtures of ethanol and acetone at 298.15 K, in terms of the evaluation of the preferential solvation of this compound by the organic solvents and water in the saturated mixtures based on the inverse Kirkwood-Buff integrals (IKBI). ...

متن کامل

Benzene-1,3-diammonium bis­(pyridine-2,6-dicarboxyl­ato)nickelate(II) penta­hydrate

In the title compound, (C(6)H(10)N(2))[Ni(C(7)H(3)NO(4))(2)]·5H(2)O, the Ni(II) ion is six-coordinated by two N and four O atoms from two pyridine-2,6-dicarboxyl-ate ligands in a distorted octa-hedral fashion. The crystal packing is stabilized by inter-molecular O-H⋯O and N-H⋯O and weak C-H⋯O hydrogen bonds and π-π inter-actions [centroid-centroid distances = 3.4669 (19) and 3.764 (2) Å].

متن کامل

Benzene-pyridine interactions predicted by the effective fragment potential method.

The accurate representation of nitrogen-containing heterocycles is essential for modeling biological systems. In this study, the general effective fragment potential (EFP2) method is used to model dimers of benzene and pyridine, complexes for which high-level theoretical data -including large basis spin-component-scaled second-order perturbation theory (SCS-MP2), symmetry-adapted perturbation t...

متن کامل

Modeling and Simulation a Catalytic Fixed Bed Reactor to Produce Ethyl Benzene from Ethanol

Ethyl benzene used increasingly each year is the raw material of producing styrene monomer. This substanceis produced from benzene alkylation with ethylene or ethanol, depending on the availability and cost of rawmaterials. In this study benzene alkylation in the presence of ethanol in a catalytic fixed bed reactor inthree states of isotherm, adiabatic and non-isotherm-non-adiabatic is mathemat...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: International journal of applied thermodynamics

سال: 2022

ISSN: ['1301-9724']

DOI: https://doi.org/10.5541/ijot.1173589