Toward real-time measurement of atmospheric mercury concentrations using cavity ring-down spectroscopy

Monitoring atmospheric particulate matter through cavity ring-down spectroscopy.

Cavity ring-down spectroscopy was explored as a means to measure atmospheric optical extinction. Ambient air was sampled through a window on the campus of the University of Florida and transported to a ring-down cell fashioned from standard stainless steel vacuum components. When a copper vapor laser operating at 10 kHz is employed, this arrangement allowed for nearly continuous monitoring of a...

Cavity-locked ring-down spectroscopy

Saturated-absorption cavity ring-down spectroscopy.

We report on a novel approach to cavity ring-down spectroscopy with the sample gas in saturated-absorption regime. This technique allows us to decouple and simultaneously retrieve the empty-cavity background and absorption signal, by means of a theoretical model that we developed and tested. The high sensitivity and frequency precision for spectroscopic applications are exploited to measure, fo...

An Introduction to Cavity Ring-Down Spectroscopy

Spectroscopy, the study of the interaction of light (electromagnetic radiation) and matter, is the most ubiquitous and precise method available to the physical scientist. Especially for isolated atoms, molecules, and small clusters, it has no peer. It is used to elucidate the structure and dynamics of quantum systems from atomic nuclei to natural proteins. Essentially everything we know about t...

Phase shift cavity ring down absorption spectroscopy

Cavity ring down absorption spectroscopy with a continuous light souree is used to measure the transition frequencies and absolute absorption coefficient of the weak b ItCv' = 2) +--X I;-Cv" = 0) transition of 02. The absorption spectrum is extracted from a measurement of the magnitude of the phase shift that an intensity modulated continuous light beam experiences upon passing through an unsta...