Trans-dichloro-2,3-naphthalenediamine bis[(2-methoxyethyl)(diphenyl)phosphine]ruthenium(II) Complex
نویسندگان
چکیده
منابع مشابه
rac-3,4-trans-Dichloro-1,2,3,4-tetrahydro-2-naphthyl acetate
The title compound, C(12)H(12)Cl(2)O(2), has a bicyclic skeleton containing cyclo-hexene and benzene fragments. The cyclo-hexene ring adopts a half-chair conformation with displacements of two atoms out of the least-squares plane of 0.311 (2) and -0.336 (2) Å. The Cl atoms are trans-positioned.
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In the title compound, [K(C(4)H(8)O)][ZrCl(2)(C(12)H(8)N)(3)(C(4)H(8)O)], the Zr atom is pseudo-octahedral, with two Cl ligands in trans positions. There is extensive interaction between the potassium cation and two of the aromatic carbazolyl ligands in eta(6) [C.K = 3.167 (3)-3.331 (3) A] and eta(2) [C.K = 3.147 (3)-3.268 (2) A] fashions.
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ژورنال
عنوان ژورنال: Molbank
سال: 2010
ISSN: 1422-8599
DOI: 10.3390/m696