Transport properties of Lennard-Jones fluids: Freezing density scaling along isotherms

نویسندگان

چکیده

It is demonstrated that properly reduced transport coefficients (self-diffusion, shear viscosity, and thermal conductivity) of Lennard-Jones fluids along isotherms exhibit quasi-universal scaling on the density divided by its value at freezing point. Moreover, this closely related to hard-sphere fluids. The Stokes-Einstein relation without hydrodynamic diameter valid in dense fluid regime. lower boundary validity can serve as a practical demarcation line between gas-like liquid-like regimes.

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ژورنال

عنوان ژورنال: Physical review

سال: 2021

ISSN: ['0556-2813', '1538-4497', '1089-490X']

DOI: https://doi.org/10.1103/physreve.103.042122