Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
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منابع مشابه
Trichodermin (12,13-epoxytrichethec-9-en-4β-yl 4-fluorobenzoate)
IN THE TITLE TRICHODERMIN COMPOUND (SYSTEMATIC NAME: 12,13-ep-oxy-trichothec-9-en-4β-yl 4-fluoro-benzoate), C(22)H(25)FO(4), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the different conformations, viz. chair and half-chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope ...
متن کاملTrichodermin (4β-acetoxy-12,13-epoxytrichothec-9-ene)
In the title natural product, C(17)H(24)O(4), which is a very potent inhibitor of protein synthesis in mammalian cells, the five-membered ring displays an envelope conformation, whereas the two six-membered rings show different conformations, viz. chair and half-chair.
متن کاملDihalogenated trichodermin (4β-acetoxy-9,10-dibromo-12,13-epoxytrichothec)
In the title dihalogenated trichodermin mol-ecule, C(17)H(24)Br(2)O(4) (systematic name: 9,10-dibromo-12,13-epoxy-trichothec-9-en-4β-yl acetate), the five-membered ring displays an envelope conformation, whereas the two six-membered rings show the same conformation, viz. chair. As for the seven-membered ring, the dihedral angle between the mean planes formed by the four C atoms of the envelope ...
متن کامل4-Desoxy-4β-(4-methoxycarbonyl-1,2,3-triazol-1-yl)podophyllotoxin dichloromethane solvate
In the title compound {systematic name: methyl 1-[12-oxo-10-(3,4,5-trimethoxy-phen-yl)-4,6,13-trioxa-tetra-cyclo-[7.7.0.0(3,7).0(11,15)]hexa-deca-1,3(7),8-trien-16-yl]-1H-1,2,3-triazole-4-carboxyl-ate dichloro-methane solvate}, C(26)H(25)N(3)O(9)·CH(2)Cl(2), the tetra-hydro-furan ring and the six-membered ring fused to it both display envelope conformations.
متن کامل(E)-3-(Anthracen-9-yl)-1-(4-bromophenyl)prop-2-en-1-one1
In the title mol-ecule, C(23)H(15)BrO, the prop-2-en-1-one unit is planar and it makes dihedral angles of 20.9 (1) and 45.8 (1)°, respectively, with the 4-bromo-phenyl ring and the anthracene ring system. The interplanar angle between the 4-bromophenyl ring and the anthracene ring system is 35.52 (7)°. In the crystal structure, mol-ecules are linked into dimers by C-H⋯Br hydrogen bonds, and the...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810028461