Triple-Decker Complexes Formed via the Weak Link Approach
نویسندگان
چکیده
منابع مشابه
Threefold symmetric trimetallic macrocycles formed via the Weak-Link Approach.
The synthesis and characterization of a new threefold symmetric hemilabile phosphino-alkylthioether ligand are described. This ligand can be used in combination with Rh(I) and Ir(I) precursor complexes to prepare 40-membered macrocyles with threefold symmetry via the Weak-Link Approach. Synthesis and characterization of two such structures are reported along with a single crystal x-ray diffract...
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Sequential reaction of two different hemilabile ligands (Ph(2)PCH(2)CH(2)X)(2)Ar (X = S, Ar = C(6)H(4) or C(6)(CH(3))(4); X = NCH(3), Ar = C(6)H(4); X = O, Ar = 9,10-C(14)H(8)) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [[1,...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2006
ISSN: 0276-7333,1520-6041
DOI: 10.1021/om0602310