Two-dimensional multimetallic sulfide nanosheets with multi-active sites to enhance polysulfide redox reactions in liquid Li2S6-based lithium-polysulfide batteries

Highly reversible lithium/dissolved polysulfide batteries with carbon nanotube electrodes.

Free standing acetylene black mesh to capture dissolved polysulfide in lithium sulfur batteries.

Herein, we report a cheap and simple approach to solve the polysulfide dissolution problem in lithium sulfur batteries. It was interestingly revealed that a simple insertion of acetylene black mesh enabled us to obtain the capacity of 1491 mA h g(-1) at initial discharge and 1062 mA h g(-1) after 50 cycles.

Two-Dimensional Nanosheets from Redox-Active Superatoms

We describe a new approach to synthesize two-dimensional (2D) nanosheets from the bottom-up. We functionalize redox-active superatoms with groups that can direct their assembly into multidimensional solids. We synthesized Co6Se8[PEt2(4-C6H4COOH)]6 and found that it forms a crystalline assembly. The solid-state structure is a three-dimensional (3D) network in which the carboxylic acids form inte...

A novel quasi-solid state electrolyte with highly effective polysulfide diffusion inhibition for lithium-sulfur batteries

Polymer solid state electrolytes are actively sought for their potential application in energy storage devices, particularly lithium metal rechargeable batteries. Herein, we report a polymer with high concentration salts as a quasi-solid state electrolyte used for lithium-sulfur cells, which shows an ionic conductivity of 1.6 mS cm(-1) at room temperature. The cycling performance of Li-S batter...

Magnetic Field-Controlled Lithium Polysulfide Semiliquid Battery with Ferrofluidic Properties.

Large-scale energy storage systems are of critical importance for electric grids, especially with the rapid increasing deployment of intermittent renewable energy sources such as wind and solar. New cost-effective systems that can deliver high energy density and efficiency for such storage often involve the flow of redox molecules and particles. Enhancing the mass and electron transport is crit...