Unconventional Approaches in Coordination Chemistry and Organometallic Reactivity
نویسندگان
چکیده
منابع مشابه
Two-state reactivity as a new concept in organometallic chemistry.
It is proposed that spin-crossing effects can dramatically affect reaction mechanisms, rate constants, branching ratios, and temperature behaviors of organometallic transformations. This phenomenon is termed two-state reactivity (TSR) and involves participation of spin inversion in the rate-determining step. While the present analysis is based on studies of transition metals under idealized con...
متن کاملOrganometallic chemistry
This Thematic Series is dedicated to the memory of Professor Peter Hofmann (Figure 1) whose research work included many seminal contributions to the field of organometallic chemistry [1-3]. Organometallic chemistry has therefore been chosen as the topic of this Thematic Series of the Beilstein Journal of Organic Chemistry. Over a period of many decades, the chemistry of metal–carbon bonds has g...
متن کاملInorganic and Organometallic Chemistry
The activities of the group comprise the synthesis, characterization and reactivity studies of inorganic, organometallic and intermetallic compounds of actinides and lanthanides in order to understand the influence of the electronic configuration and of the size of these elements in the chemical behaviour of their compounds. Reactivity properties are assessed by stoichiometric reactions and by ...
متن کاملIron–dinitrogen coordination chemistry: Dinitrogen activation and reactivity
Understanding the coordination of dinitrogen to iron is important for understanding biological nitrogen fixation aswell as for designing synthetic systems that are capable of reducing N2 to NH3 undermild conditions. This review discusses recent advances in iron–dinitrogen coordination complexes and describes the factors that contribute to the degree of activation of the coordinatedN2. The react...
متن کاملActinide organometallic chemistry.
The stoichiometric and catalytic chemistry of metal-organic compounds having actinide-to-carbon bonds is in a stage of rapid growth. Chemical, structural, and bonding characteristics have been identified which differ in interesting and informative ways from those of d-block transition element compounds.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: ACS Omega
سال: 2021
ISSN: 2470-1343,2470-1343
DOI: 10.1021/acsomega.0c05873