UNRAVELLING THE HYDROLYSIS PATHWAY OF DIORGANOTIN DIHALIDES TOWARDS MOLECULAR DIORGANOTIN OXIDES
نویسندگان
چکیده
منابع مشابه
Monoorganooxotin cage, diorganotin ladders, diorganotin double chain and triorganotin single chain formed with phosphonate and arsonate ligands.
The solvothermal reaction of n-BuSn(O)OH with PhPO(3)H(2) afforded the hexanuclear monoorganooxotin phosphonate cage, {[(n-BuSn)(3)(MeO)(3)O](2)(O(3)PPh)(4)}.MeOH 1. When the n-Bu(2)Sn(PhCO(2))(2) precursor reacted with PhPO(3)H(2) in a 1 : 1 stoichiometric ratio, the diorganotin phosphonate ladder [n-Bu(2)SnO(3)PPh](n) 2 was obtained. The reaction of [n-Bu(2)(PrO)Sn](2)O with 4-OH-3-NO(2)-C(6)...
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Tin(IV) and organotin(IV) compounds, a deceptively simple area of inorganic and metal-organic chemistry, have been receiving more attention due to the important industrial (Tammy and Georges, 2005) and environmental applications. Nitrogen, oxygen, and sulfur donor ligands have been used to enhance the biological activity of organotin derivatives (Mohammad et al., 2004; Jason et al., 2000). Also...
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ژورنال
عنوان ژورنال: Main Group Metal Chemistry
سال: 2002
ISSN: 2191-0219,0792-1241
DOI: 10.1515/mgmc.2002.25.1-2.109