Using solubility parameter analysis to understand delignification of poplar and rice straw with catalyzed organosolv fractionation processes

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Fractionation of Hemicelluloses and Lignin from Rice Straw by Combining Autohydrolysis and Optimised Mild Organosolv Delignification

An integrated strategy was followed to valorise rice straw, one of the most relevant biomass feedstocks available worldwide, to selectively recover solubilised hemicelluloses and lignin. The pathway encompassed the use of autohydrolysis to hydrolyse the hemicelluloses and an ethanol-based organosolv process to solubilise lignin. Several autohydrolysis conditions were assayed with the best resul...

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Eucalyptus globulus wood fractionation by autohydrolysis and organosolv delignification.

This work provides an assessment on the fractionation of Eucalyptus globulus wood by sequential stages of autohydrolysis (to cause the solubilization of hemicelluloses) and organosolv pulping (to dissolve lignin, leaving solids enriched in cellulose). With this approach, valuable products (hemicellulose-derived saccharides, sulphur-free lignin fragments and cellulosic substrates with low conten...

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Effective alkaline metal-catalyzed oxidative delignification of hybrid poplar

BACKGROUND Strategies to improve copper-catalyzed alkaline hydrogen peroxide (Cu-AHP) pretreatment of hybrid poplar were investigated. These improvements included a combination of increasing hydrolysis yields, while simultaneously decreasing process inputs through (i) more efficient utilization of H2O2 and (ii) the addition of an alkaline extraction step prior to the metal-catalyzed AHP pretrea...

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Development and characterization of an environmentally friendly process sequence (autohydrolysis and organosolv) for wheat straw delignification.

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Delignification of rye straw using hydrogen peroxide

Alkaline peroxide delignification of rye straw has been first investigated in this paper. The results showed that treatment of dewaxed and water-extracted rye straw with 2% H2O2 at pH 11.5 for 12 h at 20, 30, 40, 50, 60, and 70°C resulted in a dissolution of 52.7, 75.7, 81.8, 83.1, 85.8, and 87.8% of the original lignin, and 44.2, 52.5, 70.0, 70.0, 71.3, and 71.9% of the original hemicelluloses...

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ژورنال

عنوان ژورنال: BioResources

سال: 2018

ISSN: 1930-2126,1930-2126

DOI: 10.15376/biores.14.1.486-499