Valence of the Elemental Transition Metals

Valence-bond theory of compounds of transition metals.

An equation relating the strength (bondforming power) of an spd hybrid bond orbital to the angles it makes with other bond orbitals is formulated and applied in the discussion of the structures of transition-metal carbonyls and other substances by the valence-bond method. The rather simple theory gives results that agree well with those obtained by the complicated and laborious calculation of s...

Calculated stacking-fault energies of elemental metals.

Ab initio work function of elemental metals.

Electron mean free path in elemental metals

The electron mean free path k and carrier relaxation time s of the twenty most conductive elemental metals are determined by numerical integration over the Fermi surface obtained from first-principles, using constant k or s approximations and wave-vector dependent Fermi velocities vf (k). The average vf deviates considerably from the free-electron prediction, even for elements with spherical Fe...

The Effect of Transition Metals Incorporation on the Structural and Magnetic Properties of Magnesium Oxide Nanoparticles

Pure and doped magnesium oxide nanoparticles were successfully synthesized employing a sol-gel process. The synthesized nanoparticles were characterized by thermal differential analysis, X-ray powder diffraction, transmission electron microscopy, scanning electron microscope, energy-dispersive X-ray spectroscopy, and vibrating sample magnetometer. X-ray diffraction patterns confirmed the crysta...