WhyN2Molecules with Thermal Energy Abundantly Dissociate on W(100) and Not on W(110)

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Why N2 molecules with thermal energy abundantly dissociate on W(100) and not on W(110).

Low-energy N2 molecules easily dissociate on W(100) but not on W(110). In this Letter, the six-dimensional potential energy surface for the dissociation of N2 molecules on W(110) has been determined by density functional calculations. Results are compared to those of N2 dissociation on W(100). The difference in reactivity between the two faces is shown to arise from the characteristics of the p...

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ژورنال

عنوان ژورنال: Physical Review Letters

سال: 2006

ISSN: 0031-9007,1079-7114

DOI: 10.1103/physrevlett.97.056102